Info
Info
News Article

Princeton Chemists Discover More About Perovskite Instability

News

Source of thermodynamic instability found in 'rattling' behaviour

Researchers in the Cava Group at the Princeton University Department of Chemistry have discovered more about the instability in an inorganic perovskite that has attracted wide attention for its potential in creating highly efficient solar cells.

Using single crystal X-ray diffraction performed at Princeton University and X-ray pair distribution function measurements performed at the Brookhaven National Laboratory, Princeton Department of Chemistry researchers detected that the source of thermodynamic instability in the halide perovskite caesium lead iodide (CsPbI3) is the inorganic caesium atom and its 'rattling' behaviour within the crystal structure. X-ray diffraction yields a clear experimental signature of this movement.

The research, 'Understanding the Instability of the Halide Perovskite CsPbI3 through Temperature-Dependent Structural Analysis' will be published in the journal Advanced Materials.

Daniel Straus, a postdoctoral research associate in the Cava Group and lead author on the paper, explained that while caesium occupies a single site within the structure at temperatures below 150 K, it 'splits' into two sites above 175 K. Along with other structural parameters, this suggests evidence of the rattling behaviour of caesium within its iodine coordination polyhedron.

In addition, the low number of caesium-iodine contacts within the structure and the high degree of local octahedral distortion also contribute to the instability.

In the research, the single-crystal measurements characterised the average structure of the material. At Brookhaven, the X-ray pair distribution function allowed researchers to determine the behaviour of the structure on the length scale of the unit cell. (A unit cell is the smallest repeating unit in a crystal.) It is on this local level that the high degree of octahedral distortion became obvious, said Straus.

The room-temperature metastability of CsPbI3 has long been a known factor, but it had not previously been explained.

"Finding an explanation for a problem that so many people in the research community are interested in is great, and our collaboration with Brookhaven has been beyond fantastic," said Robert Cava, the Russell Wellman Moore professor of Chemistry, an expert in synthesis and structure-property characterisation.

'Remarkable' efficiencies

Currently, the dominant halide perovskite in solar energy conversion applications is based on methylammonium lead iodide, an organic-inorganic hybrid material that has been incorporated into solar cells with certified efficiencies of 25.2 percent; this rivals the efficiency of commercial silicon solar cells. While this "remarkable" efficiency drives interest, methylammonium lead iodide suffers from instability problems thought to originate from the volatile nature of the organic cation. To correct this problem, researchers have attempted to replace the organic cation with inorganic caesium, which is significantly less volatile.

However, unlike methylammonium lead iodide, the perovskite phase of caesium lead iodide is metastable at room temperature.

"If you want to make a solar cell with unmodified caesium lead iodide, it's going to be very hard to work around this and stabilise this material," said Straus. "You have to find a way to stabilise it that works around the fact that this caesium atom is a little bit too small. There are a couple ways people have tried to chemically modify CsPbI3 and they work okay. But there's no point in just trying to make solar cells out of this bulk material without doing fancy things to it."

Detailed structural information in the paper suggests methods to stabilise the perovskite phase of CsPbI3 and thus improve the stability of halide perovskite solar cells. The paper also reveals the limitations of tolerance factor models in predicting stability for halide perovskites. Most of these models currently predict that CsPbI3 should be stable.

At Brookhaven Lab

A technique known as a pair distribution function measurement, which describes the distribution of distances between atoms, helped the Princeton researchers to further understand the instability. Using Brookhaven's Pair Distribution Function (PDF) beamline at the National Synchrotron Light Source II, lead beamline scientist Milinda Abeykoon worked with samples of thermodynamically unstable CsPbI3, which he received from the Cava Lab in several sealed glass capillaries inside a container filled with dry ice.

Measuring these samples was challenging, said Abeykoon, because they would decompose quickly once removed from the dry ice.

"Thanks to the extremely bright X-ray beam and large area detectors available at the PDF beamline, I was able to measure the samples at multiple temperatures below 300 K before they degraded," said Abeykoon. "When the X-ray beam bounces off the sample, it produces a pattern characteristic of the atomic arrangement of the material. This gives us the possibility to see not only what is happening at the atomic scale, but also how the material behaves in general in one measurement."

Scientists Combine Solar And Battery Tech In One Device
Sonnedix Acquires Eliantus, A 74.7 MW Solar PV Portfolio In Spain From JZI And Elliott
Alectris Partners With Resco For All-in-one Mobile Solar O&M Tracking
RENA Diversifies With Additive Manufacturing
Semiconductor Foundry Joins RE100 And Calls On Peers To Step Up On Renewable Energy
Delta Uses ON Semi SiC Power Modules
US Scientists Build Hybrid Solar Energy Converter
Record Efficiency For Printed Perovskite Solar Cells
Sonnedix Achieves Financial Close For 5.5 MW Of Operational Capacity In The Shimane Prefecture
Electrons In The Fast Lane
Japanese Team Achieves High Perovskite Stability And Efficiency
Eversheds Sutherland Advises On Europe’s Largest Floating Solar Project
Solar Arrays To Be Installed For General Dynamics Ordnance And Tactical Systems
From Perovskites To The TeraWatt Era And A Carbon-free Energy System
FIMER Set To Strengthen Its Position In Global Solar Inverter Market
First Solar Project Leader Dan Lonetti Joins Burns & McDonnell In Arizona
Sonnedix Adds 8.2 MW To Its Italian Portfolio
CIGS: Rock Star Of Photovoltaics?
REC Group Rejects Decision By The Düsseldorf Regional Court On Alleged Patent Infringement Regarding TwinPeak Solar Cells
Princeton Chemists Discover More About Perovskite Instability
Singapore Team Develops Highest Power Conversion Perovskite Cells
BYD Announces Compatibility Of Battery-Box Premium With SMA’s Sunny Boy Storage Line
Halide Perovskites Love-hate Relationship With The Sun
ETRI Develops Eco-friendly Colour CIGS Solar Cells

Info
×
Search the news archive

To close this popup you can press escape or click the close icon.
Logo
×
Logo
×
Register - Step 1

You may choose to subscribe to the Solar + Power Magazine, the Solar + Power Newsletter, or both. You may also request additional information if required, before submitting your application.


Please subscribe me to:

 

You chose the industry type of "Other"

Please enter the industry that you work in:
Please enter the industry that you work in:
 
X
Info
X
Info
{taasPodcastNotification}